Prof. Kevin M Ryan
Biography
Professor Kevin M. Ryan holds a Personal Chair in Chemical Nanotechnology at the Department of Chemical Sciences in the School of Natural Sciences at the University of Limerick He is coordinator of the H2020 EU projects Si-Drive and NEILLSBAT in the area of Li-ion and Lithium-Sulfur batteries respectively. He is Co-Principal Investigator on SFI Centres MaREI and AMBER and funded Investigator on SSPC and Confirm. He is theme leader for the Molecular/Nano cluster at the Bernal Institute and holds SFI IVP and IRC Laureate awards. He is a native of Limerick and graduated with a BSc in 1999 and a PhD in 2003 in Chemistry from University College Cork. He subsequently held Marie Curie Fellowship positions at Merck Chemicals Southampton, UK and at the University of California, Berkeley, USA, prior to joining University of Limerick in 2006 as a Stokes Lecturer. He has published over 140academic papers with a h-index of 43 (Google Scholar) and holds several patents with research interests in semiconductor nanocrystals and nanowires for applications in electronic devices and batteries. His research group currently 5 postdoctoral researchers and 16 PhD students are based at the Bernal Institute (www.nanoresearchul.org).Research Interests
Keywords: Colloidal Nanocrystals, Nanorods, Nanowires, Silicon, Germanium, Cadmium Sulphide, Cadmium Selenide, Copper Indium Gallium Sulphide/selenide (CIGS), Dicopper-zinc-tin-tetrasulphide (CZTS), Nanorod Assembly, Electrophoretic Assembly, Charge based Assembly, Thin-films, Photoabsorbers, Lithium ion batteries.
The group research interests are in: [1] Colloidal Nanocrystals with particular emphasis on Semiconductor Nanorods and their device scale assembly by directed (Electric fields ) or non-directed for scaleable applications in photovoltaics. The group has pioneered routes whereby the nanorods can be assembled from solution such that each rod is Vertically Aligned and Close packed (-allowing the formation of a forest of nanoscale photo absorbers directly from solution). As the semiconductors are pot synthesized and processed from solution (-similar to an ink) they offer a low cost protocol to thin-film devices. The group has recently extended the nanorod synthesis and assembly protocols to copper indium gallium sulfide/selenide (CIGS) and dicopper-zinc-tin-tetrasulphide (CZTS). These materials are attractive for their high efficiencies in thin-film devices and CZTS in particular is viewed as an attractive long term solution for low cost photovoltaics as all the elements are in high natural abundance. Funding for this work is through a Science Foundation Ireland Principal Investigator Award and through the SFI Strategic Research Cluster in Solar Energy Conversion.
[2] Low cost solution synthesis of silicon and germanium nanowires by seeded and non-seeded strategies particularly targeted towards generating wires in high yield. We have developed a novel synthetic protocol that allows the growth of group 14 nanowires in the vapor phase of high boiling point solvents in glass ware based apparatus allowing high purity nanowires to be formed either with or without catalysts . Recently we have used indium and tin catalysts for form high density arrays of silicon and germanium wires on substrates and have extended the syntheses to metal silicide structures. Control over nanowire length for the formation of nanorods was achieved by a modification of this synthesis protocol. Investigation of nanowires of germanium as anodes for Lithium ion batteries is funded through the European Union GREENLION project with a consortium of 14 partners including large car manufactures such as SEAT and Volkswagen. The investigation of non-seeded nanowires for ICT is funded through an SFI Principal Investigator grant with industry support from Intel Ireland. For additional information see featured posts and full publication listings.
Professional Activities
Patent
- 2012 US8138067 - Method and System for Synthesis of Semiconductor Nanowires
- 2002 US6699797 - Method of Fabrication of Low Dielectric Constant Porous Metal Silicate Film
Award
- 2011 - MSSI Researcher Award
- 2001 - Institute of Chemistry of Ireland Golden Jubilee Award
Employment
- 2006 University of California Berkeley - Marie Curie Research Fellow
- 2003 Merck Chemicals Ltd. - Marie Curie Fellow
- 2002 University College Cork - Enterprise Ireland Research Fellow
Association
- 2003 Association of Reserchers who have receive a Marie Curie Award, Marie Curie Fellowship Association
- 2001 Member, Royal Society of Chemistry
Education
- 2003 University College Cork - Ph.D.
- 1999 University College Cork - B.Sc.
Peer Reviewed Journals
Production of hydrochlorothiazide nanoparticles with increased permeability using top-spray coating process
Verma, V;Patel, P;Ryan, KM;Hudson, S;Padrela, L (2023) Production of hydrochlorothiazide nanoparticles with increased permeability using top-spray coating process. AMSTERDAM : ELSEVIER Journal Of Supercritical Fluids
Thermodynamic solubility of celecoxib in organic solvents
Verma, V;Soto, R;Bhattacharya, S;Thompson, D;Ryan, KM;Padrela, L (2022) Thermodynamic solubility of celecoxib in organic solvents. CAMBRIDGE : ROYAL SOC CHEMISTRY Crystengcomm :698-710
Production of biopharmaceutical dried-powders using supercritical CO2 technology
O'Sullivan, A;Ryan, KM;Padrela, L (2022) Production of biopharmaceutical dried-powders using supercritical CO2 technology. AMSTERDAM : ELSEVIER Journal Of Supercritical Fluids
Alternative anodes for low temperature lithium-ion batteries
Collins, GA;Geaney, H;Ryan, KM (2021) Alternative anodes for low temperature lithium-ion batteries. CAMBRIDGE Journal Of Materials Chemistry A :14172-14213
Highly Efficient Oxygen Evolution Reaction Enabled by Phosphorus Doping of the Fe Electronic Structure in Iron-Nickel Selenide Nanosheets
Huang, Y;Jiang, LW;Shi, BY;Ryan, KM;Wang, JJ (2021) Highly Efficient Oxygen Evolution Reaction Enabled by Phosphorus Doping of the Fe Electronic Structure in Iron-Nickel Selenide Nanosheets. HOBOKEN : WILEY Advanced Science
A Nanowire Nest Structure Comprising Copper Silicide and Silicon Nanowires for Lithium-Ion Battery Anodes with High Areal Loading
Collins, GA;Kilian, S;Geaney, H;Ryan, KM (2021) A Nanowire Nest Structure Comprising Copper Silicide and Silicon Nanowires for Lithium-Ion Battery Anodes with High Areal Loading. WEINHEIM : WILEY-V C H VERLAG GMBH Small
Pharmaceutical Nanoparticle Isolation Using CO2-Assisted Dynamic Bed Coating.
Verma V;Ryan KM;Padrela L; (2020) Pharmaceutical Nanoparticle Isolation Using CO2-Assisted Dynamic Bed Coating.. International journal of pharmaceutics
Influence of Carbonate-Based Additives on the Electrochemical Performance of Si NW Anodes Cycled in an Ionic Liquid Electrolyte.
Stokes K;Kennedy T;Kim GT;Geaney H;Storan D;Laffir F;Appetecchi GB;Passerini S;Ryan KM; (2020) Influence of Carbonate-Based Additives on the Electrochemical Performance of Si NW Anodes Cycled in an Ionic Liquid Electrolyte.. Nano Letters
Direct visualization of phase-matched efficient second harmonic and broadband sum frequency generation in hybrid plasmonic nanostructures.
Li Z;Corbett B;Gocalinska A;Pelucchi E;Chen W;Ryan KM;Khan P;Silien C;Xu H;Liu N; (2020) Direct visualization of phase-matched efficient second harmonic and broadband sum frequency generation in hybrid plasmonic nanostructures.. Light-Science & Applications
Insight into the Role of Additives in Controlling Polymorphic Outcome: A CO2-Antisolvent Crystallization Process of Carbamazepine
Padrela, L,Zeglinski, J,Ryan, KM (2017) Insight into the Role of Additives in Controlling Polymorphic Outcome: A CO2-Antisolvent Crystallization Process of Carbamazepine. Crystal Growth & Design :4544-4553
The selective synthesis of nickel germanide nanowires and nickel germanide seeded germanium nanowires within a solvent vapour growth system
Sheehan, M,Guo, YN,Flynn, G,Geaney, H,Ryan, KM (2017) The selective synthesis of nickel germanide nanowires and nickel germanide seeded germanium nanowires within a solvent vapour growth system. Crystengcomm :2072-2078
Assembling Ordered Nanorod Superstructures and Their Application as Microcavity Lasers
Liu, P,Singh, S,Guo, YN,Wang, JJ,Xu, HX,Silien, C,Liu, N,Ryan, KM (2017) Assembling Ordered Nanorod Superstructures and Their Application as Microcavity Lasers. Scientific Reports
Understanding the influence of electrolyte additives on the electrochemical performance and morphology evolution of silicon nanowire based lithium-ion battery anodes
Kennedy, T,Brandon, M,Laffir, F,Ryan, KM (2017) Understanding the influence of electrolyte additives on the electrochemical performance and morphology evolution of silicon nanowire based lithium-ion battery anodes. Journal Of Power Sources :601-610
Solution synthesis of lead seeded germanium nanowires and branched nanowire networks and their application as Li-ion battery anodes
Flynn, G,Palaniappan, K,Sheehan, M,Kennedy, T,Ryan, KM (2017) Solution synthesis of lead seeded germanium nanowires and branched nanowire networks and their application as Li-ion battery anodes. Nanotechnology
Direct Synthesis of Alloyed Si1-xGex Nanowires for Performance-Tunable Lithium Ion Battery Anodes
Stokes, K,Geaney, H,Flynn, G,Sheehan, M,Kennedy, T,Ryan, KM (2017) Direct Synthesis of Alloyed Si1-xGex Nanowires for Performance-Tunable Lithium Ion Battery Anodes. Acs Nano :10088-10096
Behavior of Germanium and Silicon Nanowire Anodes with Ionic Liquid Electrolytes
Kim, GT,Kennedy, T,Brandon, M,Geaney, H,Ryan, KM,Passerini, S,Appetecchi, GB (2017) Behavior of Germanium and Silicon Nanowire Anodes with Ionic Liquid Electrolytes. Acs Nano :5933-5943
Temperature controlled shape evolution of iron oxide nanostructures in HMTA media
Zhao, B,Ryan, KM,O'Reilly, E,McCarthy, C (2017) Temperature controlled shape evolution of iron oxide nanostructures in HMTA media. Rsc Advances :26328-26334
Formation of reworkable nanocomposite adhesives by dielectric heating of epoxy resin embedded Fe3O4 hollow spheres
Zhao, B,Hardiman, M,Ryan, KM,O'Reilly, E,McCarthy, C (2016) Formation of reworkable nanocomposite adhesives by dielectric heating of epoxy resin embedded Fe3O4 hollow spheres. Crystengcomm :6096-6101
Complete assembly of Cu2ZnSnS4 (CZTS) nanorods at substrate interfaces using a combination of self and directed organisation
Liu, P,Singh, S,Bree, G,Ryan, KM (2016) Complete assembly of Cu2ZnSnS4 (CZTS) nanorods at substrate interfaces using a combination of self and directed organisation. Chemical Communications :11587-11590
Heteroaggregation assisted wet synthesis of core-shell silver-silica-cadmium selenide nanowires
Pita, IA,Singh, S,Silien, C,Ryan, KM,Liu, N (2016) Heteroaggregation assisted wet synthesis of core-shell silver-silica-cadmium selenide nanowires. Nanoscale :1200-1209
Colloidal synthesis of Cu2SnSe3 nanocrystals with structure induced shape evolution
Wang, JJ,Ryan, KM (2016) Colloidal synthesis of Cu2SnSe3 nanocrystals with structure induced shape evolution. Crystengcomm :3161-3169
Solvent Vapor Growth of Axial Heterostructure Nanowires with Multiple Alternating Segments of Silicon and Germanium
Flynn, G,Ramasse, QM,Ryan, KM (2016) Solvent Vapor Growth of Axial Heterostructure Nanowires with Multiple Alternating Segments of Silicon and Germanium. Nano Letters :374-380
Advances in the Application of Silicon and Germanium Nanowires for High-Performance Lithium-Ion Batteries
Kennedy, T,Brandon, M,Ryan, KM (2016) Advances in the Application of Silicon and Germanium Nanowires for High-Performance Lithium-Ion Batteries. Advanced Materials :5696-5704
Selective Phase Transformation of Wurtzite Cu2ZnSn(SSe)(4) (CZTSSe) Nanocrystals into Zinc-Blende and Kesterite Phases by Solution and Solid State Transformations
Singh, S,Brandon, M,Liu, P,Laffir, F,Redington, W,Ryan, KM (2016) Selective Phase Transformation of Wurtzite Cu2ZnSn(SSe)(4) (CZTSSe) Nanocrystals into Zinc-Blende and Kesterite Phases by Solution and Solid State Transformations. Chemistry Of Materials :5055-5062
Nanowire Heterostructures Comprising Germanium Stems and Silicon Branches as High-Capacity Li-Ion Anodes with Tunable Rate Capability
Kennedy, T,Bezuidenhout, M,Palaniappan, K,Stokes, K,Brandon, M,Ryan, KM (2015) Nanowire Heterostructures Comprising Germanium Stems and Silicon Branches as High-Capacity Li-Ion Anodes with Tunable Rate Capability. Acs Nano :7456-7465
Colloidal Cu2ZnSn(SSe)(4) (CZTSSe) Nanocrystals: Shape and Crystal Phase Control to Form Dots, Arrows, Ellipsoids, and Rods
Singh, S,Liu, P,Singh, A,Coughlan, C,Wang, JJ,Lusi, M,Ryan, KM (2015) Colloidal Cu2ZnSn(SSe)(4) (CZTSSe) Nanocrystals: Shape and Crystal Phase Control to Form Dots, Arrows, Ellipsoids, and Rods. Chemistry Of Materials :4742-4748
Insights into the Electrophoretic Deposition of Colloidal II-VI Nanorods: Optimization for Vertically and Horizontally Aligned Assemblies
Gill, E,Liu, P,Ryan, KM (2015) Insights into the Electrophoretic Deposition of Colloidal II-VI Nanorods: Optimization for Vertically and Horizontally Aligned Assemblies. Journal Of The Electrochemical Society :3019-3024
Solution Synthesis and Assembly of Wurtzite-Derived Cu-In-Zn-S Nanorods with Tunable Composition and Band Gap
Singh, A,Coughlan, C,Milliron, DJ,Ryan, KM (2015) Solution Synthesis and Assembly of Wurtzite-Derived Cu-In-Zn-S Nanorods with Tunable Composition and Band Gap. Chemistry Of Materials :1517-1523
Occurrence of Polytypism in Compound Colloidal Metal Chalcogenide Nanocrystals, Opportunities, and Challenges
Singh, S,Ryan, KM (2015) Occurrence of Polytypism in Compound Colloidal Metal Chalcogenide Nanocrystals, Opportunities, and Challenges. Journal Of Physical Chemistry Letters :3141-3148
A facile phosphine-free colloidal synthesis of Cu2SnS3 and Cu2ZnSnS4 nanorods with a controllable aspect ratio
Wang, JJ,Liu, P,Ryan, KM (2015) A facile phosphine-free colloidal synthesis of Cu2SnS3 and Cu2ZnSnS4 nanorods with a controllable aspect ratio. Chemical Communications :13810-13813
Synthesis of silicon-germanium axial nanowire heterostructures in a solvent vapor growth system using indium and tin catalysts
Mullane, E,Geaney, H,Ryan, KM (2015) Synthesis of silicon-germanium axial nanowire heterostructures in a solvent vapor growth system using indium and tin catalysts. Physical chemistry chemical physics : PCCP :6919-6924
Complete study of the composition and shape evolution in the synthesis of Cu2ZnSnS4 (CZTS) semiconductor nanocrystals
Coughlan, C,Ryan, KM (2015) Complete study of the composition and shape evolution in the synthesis of Cu2ZnSnS4 (CZTS) semiconductor nanocrystals. Crystengcomm :6914-6922
High density and patternable growth of silicon, germanium and alloyed SiGe nanowires by a rapid anneal protocol
Bezuidenhout, M,Kennedy, T,Belochapkine, S,Guo, Y,Mullane, E,Kiely, PA,Ryan, KM (2015) High density and patternable growth of silicon, germanium and alloyed SiGe nanowires by a rapid anneal protocol. Journal Of Materials Chemistry C :7455-7462
Pd Clusters Supported on Amorphous, Low-Porosity Carbon Spheres for Hydrogen Production from Formic Acid
Bulushev, DA,Bulusheva, LG,Beloshapkin, S,O'Connor, T,Okotrub, AV,Ryan, KM (2015) Pd Clusters Supported on Amorphous, Low-Porosity Carbon Spheres for Hydrogen Production from Formic Acid. ACS Applied Materials & Interfaces :8719-8726
Promoting cell proliferation using water dispersible germanium nanowires.
Bezuidenhout M, Liu P, Singh S, Kiely M, Ryan KM, Kiely PA (2014) Promoting cell proliferation using water dispersible germanium nanowires.. Plos One
Phase-transition-driven growth of compound semiconductor crystals from ordered metastable nanorods
Mainz, R,Singh, A,Levcenko, S,Klaus, M,Genzel, C,Ryan, KM,Unold, T (2014) Phase-transition-driven growth of compound semiconductor crystals from ordered metastable nanorods. Nature Communications
A Rapid, Solvent-Free Protocol for the Synthesis of Germanium Nanowire Lithium-Ion Anodes with a Long Cycle Life and High Rate Capability
Mullane, E,Kennedy, T,Geaney, H,Ryan, KM (2014) A Rapid, Solvent-Free Protocol for the Synthesis of Germanium Nanowire Lithium-Ion Anodes with a Long Cycle Life and High Rate Capability. ACS Applied Materials & Interfaces :18800-18807
High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network
Kennedy, T,Mullane, E,Geaney, H,Osiak, M,O'Dwyer, C,Ryan, KM (2014) High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network. Nano Letters :716-723
Assembly of binary, ternary and quaternary compound semiconductor nanorods: From local to device scale ordering influenced by surface charge
Ryan, KM,Singh, S,Liu, P,Singh, A (2014) Assembly of binary, ternary and quaternary compound semiconductor nanorods: From local to device scale ordering influenced by surface charge. Crystengcomm :9446-9454
Complete Colloidal Synthesis of Cu2SnSe3 Nanocrystals with Crystal Phase and Shape Control
Wang, JJ,Liu, P,Seaton, CC,Ryan, KM (2014) Complete Colloidal Synthesis of Cu2SnSe3 Nanocrystals with Crystal Phase and Shape Control. Journal of the American Chemical Society :7954-7960
Crystallization of Semiconductor Nanorods into Perfectly Faceted Hexagonal Superstructures
Singh, A,Ryan, KM (2013) Crystallization of Semiconductor Nanorods into Perfectly Faceted Hexagonal Superstructures. Particle & Particle Systems Characterization :624-629
Core-Shell Tin Oxide, Indium Oxide, and Indium Tin Oxide Nanoparticles on Silicon with Tunable Dispersion: Electrochemical and Structural Characteristics as a Hybrid Li-Ion Battery Anode
Osiak, MJ,Armstrong, E,Kennedy, T,Torres, CMS,Ryan, KM,O'Dwyer, C (2013) Core-Shell Tin Oxide, Indium Oxide, and Indium Tin Oxide Nanoparticles on Silicon with Tunable Dispersion: Electrochemical and Structural Characteristics as a Hybrid Li-Ion Battery Anode. ACS Applied Materials & Interfaces :8195-8202
Colloidal Synthesis of Cu2SnSe3 Tetrapod Nanocrystals
Wang, JJ,Singh, A,Liu, P,Singh, S,Coughlan, C,Guo, YN,Ryan, KM (2013) Colloidal Synthesis of Cu2SnSe3 Tetrapod Nanocrystals. Journal Of The American Chemical Society :7835-7838
Systematic Study into the Synthesis and Shape Development in Colloidal CuInxGa1-xS2 Nanocrystals
Coughlan, C,Singh, A,Ryan, KM (2013) Systematic Study into the Synthesis and Shape Development in Colloidal CuInxGa1-xS2 Nanocrystals. Chemistry Of Materials :653-661
Solution phase synthesis of silicon and germanium nanowires
Geaney, H,Mullane, E,Ryan, KM (2013) Solution phase synthesis of silicon and germanium nanowires. Journal Of Materials Chemistry C :4996-5007
Synthesis of Tin Catalyzed Silicon and Germanium Nanowires in a Solvent-Vapor System and Optimization of the Seed/Nanowire Interface for Dual Lithium Cycling
Mullane, E,Kennedy, T,Geaney, H,Dickinson, C,Ryan, KM (2013) Synthesis of Tin Catalyzed Silicon and Germanium Nanowires in a Solvent-Vapor System and Optimization of the Seed/Nanowire Interface for Dual Lithium Cycling. Chemistry Of Materials :1816-1822
Colloidal synthesis of homogeneously alloyed CdSexS1-x nanorods with compositionally tunable photoluminescence
Singh, S,Singh, A,Palaniappan, K,Ryan, KM (2013) Colloidal synthesis of homogeneously alloyed CdSexS1-x nanorods with compositionally tunable photoluminescence. Chemical Communications :10293-10295
Atomically Abrupt Silicon-Germanium Axial Heterostructure Nanowires Synthesized in a Solvent Vapor Growth System
Geaney, H,Mullane, E,Ramasse, QM,Ryan, KM (2013) Atomically Abrupt Silicon-Germanium Axial Heterostructure Nanowires Synthesized in a Solvent Vapor Growth System. Nano Letters :1675-1680
Fabrication of Noble metal-semiconductor hybrid nanostructures using phase transfer
Bala, T,Singh, A,Sanyal, A,O'Sullivan, C,Laffir, F,Coughlan, C,Ryan, KM (2013) Fabrication of Noble metal-semiconductor hybrid nanostructures using phase transfer. Nano Research :121-130
Epitaxial growth of visible to infra-red transparent conducting In2O3 nanodot dispersions and reversible charge storage as a Li-ion battery anode
Osiak, M,Khunsin, W,Armstrong, E,Kennedy, T,Torres, CMS,Ryan, KM,O'Dwyer, C (2013) Epitaxial growth of visible to infra-red transparent conducting In2O3 nanodot dispersions and reversible charge storage as a Li-ion battery anode. Nanotechnology
Compositionally Tunable Photoluminescence Emission in Cu2ZnSn(S1-xSex)(4) Nanocrystals
Singh, A,Singh, S,Levcenko, S,Unold, T,Laffir, F,Ryan, KM (2013) Compositionally Tunable Photoluminescence Emission in Cu2ZnSn(S1-xSex)(4) Nanocrystals. Angewandte Chemie-International Edition :9120-9124
Highly Ordered Nanorod Assemblies Extending over Device Scale Areas and in Controlled Multilayers by Electrophoretic Deposition
Singh, A,English, NJ,Ryan, KM (2013) Highly Ordered Nanorod Assemblies Extending over Device Scale Areas and in Controlled Multilayers by Electrophoretic Deposition. Journal Of Physical Chemistry B :1608-1615
Colloidal Synthesis of Wurtzite Cu2ZnSnS4 Nanorods and Their Perpendicular Assembly
Singh, A,Geaney, H,Laffir, F,Ryan, KM (2012) Colloidal Synthesis of Wurtzite Cu2ZnSnS4 Nanorods and Their Perpendicular Assembly. Journal Of The American Chemical Society :2910-2913
Growth of Crystalline Copper Silicide Nanowires in High Yield within a High Boiling Point Solvent System
Geaney, H,Dickinson, C,O'Dwyer, C,Mullane, E,Singh, A,Ryan, KM (2012) Growth of Crystalline Copper Silicide Nanowires in High Yield within a High Boiling Point Solvent System. Chemistry Of Materials :4319-4325
Assembly of CuIn1-xGaxS2 Nanorods into Highly Ordered 2D and 3D Superstructures
Singh, A,Coughlan, C,Laffir, F,Ryan, KM (2012) Assembly of CuIn1-xGaxS2 Nanorods into Highly Ordered 2D and 3D Superstructures. Acs Nano :6977-6983
High Density Growth of Indium seeded Silicon Nanowires in the Vapor phase of a High Boiling Point Solvent
Geaney, H,Kennedy, T,Dickinson, C,Mullane, E,Singh, A,Laffir, F,Ryan, KM (2012) High Density Growth of Indium seeded Silicon Nanowires in the Vapor phase of a High Boiling Point Solvent. Chemistry Of Materials :2204-2210
Size controlled growth of germanium nanorods and nanowires by solution pyrolysis directly on a substrate
Mullane, E,Geaney, H,Ryan, KM (2012) Size controlled growth of germanium nanorods and nanowires by solution pyrolysis directly on a substrate. Chemical Communications :5446-5448
Insight into the 3D Architecture and Quasicrystal Symmetry of Multilayer Nanorod Assemblies from Moire Interference Patterns
Singh, A,Dickinson, C,Ryan, KM (2012) Insight into the 3D Architecture and Quasicrystal Symmetry of Multilayer Nanorod Assemblies from Moire Interference Patterns. Acs Nano :3339-3345
Controlled semiconductor nanorod assembly from solution: influence of concentration, charge and solvent nature
Singh, A; Gunning, RD; Ahmed, S; Barrett, CA; English, NJ; Garate, JA; Ryan, KM (2012) Controlled semiconductor nanorod assembly from solution: influence of concentration, charge and solvent nature. Journal Of Materials Chemistry :1562-1569
Role of Defects and Growth Directions in the Formation of Periodically Twinned and Kinked Unseeded Germanium Nanowires
Geaney, H; Dickinson, C; Weng, WH; Kiely, CJ; Barrett, CA; Gunning, RD; Ryan, KM (2011) Role of Defects and Growth Directions in the Formation of Periodically Twinned and Kinked Unseeded Germanium Nanowires. Crystal Growth & Design :3266-3272
High Density Germanium Nanowire Growth Directly from Copper Foil by Self-Induced Solid Seeding
Geaney, H; Dickinson, C; Barrett, CA; Ryan, KM (2011) High Density Germanium Nanowire Growth Directly from Copper Foil by Self-Induced Solid Seeding. Chemistry Of Materials :4838-4843
Protein immobilisation on perpendicularly aligned gold tipped nanorod assemblies
O'Sullivan, C; Crilly, S; Laffir, FR; Singh, A; Magner, E; Ryan, KM (2011) Protein immobilisation on perpendicularly aligned gold tipped nanorod assemblies. Chemical Communications :2655-2657
Electrophoretic Deposition of Poly(3-decylthiophene) onto Gold-Mounted Cadmium Selenide Nanorods
Garate, JA; English, NJ; Singh, A; Ryan, KM; Mooney, DA; MacElroy, JMD (2011) Electrophoretic Deposition of Poly(3-decylthiophene) onto Gold-Mounted Cadmium Selenide Nanorods. Langmuir :13506-13513
Perpendicular growth of catalyst-free germanium nanowire arrays
Barrett, CA; Geaney, H; Gunning, RD; Laffir, FR; Ryan, KM (2011) Perpendicular growth of catalyst-free germanium nanowire arrays. Chemical Communications :3843-3845
An ac susceptibility study in capped Ni/Ni(OH)(2) core-shell nanoassemblies: dual peak observations
Godsell, JF; Bala, T; Ryan, KM; Roy, S (2011) An ac susceptibility study in capped Ni/Ni(OH)(2) core-shell nanoassemblies: dual peak observations. Journal Of Physics D-Applied Physics
Complete Synthesis of Germanium Nanocrystal Encrusted Carbon Colloids in Supercritical CO2 and their Superhydrophobic Properties
Barrett, CA; Singh, A; Murphy, JA; O'Sullivan, C; Buckley, DN; Ryan, KM (2011) Complete Synthesis of Germanium Nanocrystal Encrusted Carbon Colloids in Supercritical CO2 and their Superhydrophobic Properties. Langmuir :11166-11173
A facile spin-cast route for cation exchange of multilayer perpendicularly-aligned nanorod assemblies
Kelly, D; Singh, A; Barrett, CA; O'Sullivan, C; Coughlan, C; Laffir, FR; O'Dwyer, C; Ryan, KM (2011) A facile spin-cast route for cation exchange of multilayer perpendicularly-aligned nanorod assemblies. Nanoscale :4580-4583
Silver tip formation on colloidal CdSe nanorods by a facile phase transfer protocol
Bala, T; Sanyal, A; Singh, A; Kelly, D; O'Sullivan, C; Laffir, F; Ryan, KM (2011) Silver tip formation on colloidal CdSe nanorods by a facile phase transfer protocol. Journal Of Materials Chemistry :6815-6820
Size controlled gold tip growth onto II-VI nanorods
O'Sullivan, C; Gunning, RD; Barrett, CA; Singh, A; Ryan, KM (2010) Size controlled gold tip growth onto II-VI nanorods. Journal Of Materials Chemistry :7875-7880
Metal surface nucleated supercritical fluid-solid-solid growth of Si and Ge/SiO(x) core-shell nanowires
Barrett, CA; Gunning, RD; Hantschel, T; Arstila, K; O'Sullivan, C; Geaney, H; Ryan, KM (2010) Metal surface nucleated supercritical fluid-solid-solid growth of Si and Ge/SiO(x) core-shell nanowires. Journal Of Materials Chemistry :135-144
The Role of Texturing and Densification on Optical Transmittance of Hydroxyapatite Ceramics
Gandhi, AA; Gunning, RD; Ryan, KM; Tofail, SAM (2010) The Role of Texturing and Densification on Optical Transmittance of Hydroxyapatite Ceramics. Journal Of The American Ceramic Society :3773-3777
Directing semiconductor nanorod assembly into 1D or 2D supercrystals by altering the surface charge
Singh, A; Gunning, RD; Sanyal, A; Ryan, KM (2010) Directing semiconductor nanorod assembly into 1D or 2D supercrystals by altering the surface charge. Chemical Communications :7193-7195
A multi-rate kinetic model for spontaneous oriented attachment of CdS nanorods
Gunning, RD; O'Sullivan, C; Ryan, KM (2010) A multi-rate kinetic model for spontaneous oriented attachment of CdS nanorods. Physical Chemistry Chemical Physics :12430-12435
Spontaneous Room Temperature Elongation of CdS and Ag(2)S Nanorods via Oriented Attachment
O'Sullivan, C; Gunning, RD; Sanyal, A; Barrett, CA; Geaney, H; Laffir, FR; Ahmed, S; Ryan, KM (2009) Spontaneous Room Temperature Elongation of CdS and Ag(2)S Nanorods via Oriented Attachment. Journal Of The American Chemical Society :12250-12257
The evolution of pseudo-spherical silicon nanocrystals to tetrahedra, mediated by phosphonic acid surfactants
Barrett, CA; Dickinson, C; Ahmed, S; Hantschel, T; Arstila, K; Ryan, KM (2009) The evolution of pseudo-spherical silicon nanocrystals to tetrahedra, mediated by phosphonic acid surfactants. Nanotechnology
Block copolymer mediated stabilization of sub-5 nm superparamagnetic nickel nanoparticles in an aqueous medium
Bala, T; Gunning, RD; Venkatesan, M; Godsell, JF; Roy, S; Ryan, KM (2009) Block copolymer mediated stabilization of sub-5 nm superparamagnetic nickel nanoparticles in an aqueous medium. Nanotechnology
Water dispersible semiconductor nanorod assemblies via a facile phase transfer and their application as fluorescent biomarkers
Sanyal, A; Bala, T; Ahmed, S; Singh, A; Piterina, AV; McGloughlin, TM; Laffir, FR; Ryan, KM (2009) Water dispersible semiconductor nanorod assemblies via a facile phase transfer and their application as fluorescent biomarkers. Journal Of Materials Chemistry :8974-8981
Centimetre scale assembly of vertically aligned and close packed semiconductor nanorods from solution
Ahmed, S; Ryan, KM (2009) Centimetre scale assembly of vertically aligned and close packed semiconductor nanorods from solution. Chemical Communications :6421-6423
Gold tip formation on perpendicularly aligned semiconductor nanorod assemblies
O'Sullivan, C; Ahmed, S; Ryan, KM (2008) Gold tip formation on perpendicularly aligned semiconductor nanorod assemblies. Journal Of Materials Chemistry :5218-5222
Close-Packed Gold-Nanocrystal Assemblies Deposited with Complete Selectivity into Lithographic Trenches
Ahmed, S; Ryan, KM (2008) Close-Packed Gold-Nanocrystal Assemblies Deposited with Complete Selectivity into Lithographic Trenches. Advanced Materials :4745-+
Self-assembly of vertically aligned nanorod supercrystals using highly oriented pyrolytic graphite
Ahmed, S; Ryan, KM (2007) Self-assembly of vertically aligned nanorod supercrystals using highly oriented pyrolytic graphite. Nano Letters :2480-2485
Electric-field-assisted assembly of perpendicularly oriented nanorod superlattices
Ryan K.M., Mastroianni A., Stancil K.A., Liu H., Alivisatos A.P. (2006) Electric-field-assisted assembly of perpendicularly oriented nanorod superlattices. Nano Letters :1479-1482
Electric Field Assisted Assembly of Perpendicular Oriented Nanorod Superlattices
Ryan, KM; Mastroianni, A; Stancil, KA; Liu, H; Alivisatos, AP (2006) Electric Field Assisted Assembly of Perpendicular Oriented Nanorod Superlattices. Nano Letters :1479-1482
Controlling Morphological, Orientational and Material Properties of Mesoporous Aluminosilicate Films
Ryan, KM; Lyons, D M Holmes, J D Farrell, R Brennan, E Morris, MA; (2005) Controlling Morphological, Orientational and Material Properties of Mesoporous Aluminosilicate Films. Studies In Surface Science And Catalysis :303-314
Compact Strain-sensitive flexible photonic crystals for sensors
Pursanien, OL; Baumberg, JJ; Ryan, KM; Bauer, J; Winkler, H; Viel, B; Ruhl, T (2005) Compact Strain-sensitive flexible photonic crystals for sensors. Applied Physics Letters :101902-
Periodic Binary Si:Ti, Si:Al Mixed Macroporous Oxides with Ultra-High Heteroatom loading: A Facile Sol-Gel Approach
Hant, SH; Attard, GA; Riddle, R; Ryan, KM (2005) Periodic Binary Si:Ti, Si:Al Mixed Macroporous Oxides with Ultra-High Heteroatom loading: A Facile Sol-Gel Approach. Chemistry Of Materials :1434-
Conductive films of ordered nanowire arrays
Ziegler, K J Polyakov, B Kulharni, J Ryan, KM; Morris, MA; Erts, D Holmes, J D (2004) Conductive films of ordered nanowire arrays. J. Materials Chemistry :585-589
Pore expansion in mesoporous silicas using supercritical carbon dioxide
Hanrahan, JP; Copley, MP; Ryan, KM; Morris, MA; Holmes, JD (2004) Pore expansion in mesoporous silicas using supercritical carbon dioxide. Chemistry Of Materials :424-427
The Synthesis of Matrices of Embedded Semiconductor Nanowires
Ziegler, KJ; Ryan, KM; Rice, R; Crowley, TA; Erts, D; Olin, H; Patterson, J; Spalding, TR; Holmes, JD; Morris, MA (2004) The Synthesis of Matrices of Embedded Semiconductor Nanowires. Faraday Special Discussions Of The Chemical Soc. :311-326
Supercritical fluid preparation of copper nanotubes and nanowires using mesoporous templates
Ziegler, KJ; Harrington, PA; Ryan, KM; Crowley, TA; Holmes, JD; Morris, MA (2003) Supercritical fluid preparation of copper nanotubes and nanowires using mesoporous templates. Journal Of Physics-Condensed Matter :8303-8314
Measurements of the lattice constant of ceria when doped with lanthana and praseodymia-the possibility of local defect ordering and the observation of extensive phase separation
Ryan, KM; McGrath, JP; Farrell, RA; O'Neill, WM; Barnes, CJ; Morris, MA (2003) Measurements of the lattice constant of ceria when doped with lanthana and praseodymia-the possibility of local defect ordering and the observation of extensive phase separation. Journal Of Physics-Condensed Matter :49-58
Three-dimensional architectures of ultra-high density semiconductor nanowires deposited on chip
Ryan, KM; Erts, D; Olin, H; Morris, MA; Holmes, JD (2003) Three-dimensional architectures of ultra-high density semiconductor nanowires deposited on chip. J. Am. Chem.Soc. :6284-6288
The preparation of ordered mesoporous ceria with advanced stability
Lyons, DM; Morris, MA; Ryan, KM (2002) The preparation of ordered mesoporous ceria with advanced stability. J. Materials Chemistry :811-816
The use of templated mesoporous materials as templates for the development of ordered arrangements of nanowires and nanorods of electronically important materials
Ryan, KM; Holmes, JD; Crowley, TA; Morris, MA (2002) The use of templated mesoporous materials as templates for the development of ordered arrangements of nanowires and nanorods of electronically important materials. Studies In Surface Science And Catalysis :337-343
Control of pore morphology in mesoporous silicas synthesised from triblock copolymer templates
Ryan, KM; Coleman, NRB; Lyons, DM; Hanrahan, JP; Spalding, TR; Morris, MA; Steytler, DC; Heenan, RK; Holmes, JD (2002) Control of pore morphology in mesoporous silicas synthesised from triblock copolymer templates. Langmuir :4996-5001
Tailoring the Optical Properties of nanowires through strain
Lyons, DM; Ryan, KM; Morris, MA; Holmes, JD (2002) Tailoring the Optical Properties of nanowires through strain. Nano Letters :811-816
The formation of dimensionally ordered germanium nanowires withing mesoporous silicas
Coleman, NRB; Ryan, KM; Spalding, TR; Holmes, JD; Morris, MA (2001) The formation of dimensionally ordered germanium nanowires withing mesoporous silicas. Chemical Physics Letters :1-6
Synthesis and Characterisation of dimensionally ordered semiconductor nanowires within mesoporous silica
Coleman, NRB; Sullivan, N; Ryan, KM; Crowley, TA; Spalding, TR; Steytler, DC; Morris, MA; Holmes, JD (2001) Synthesis and Characterisation of dimensionally ordered semiconductor nanowires within mesoporous silica. J. Am. Chem.Soc. :7010-7016
Books
Book Chapters
Macroporous Materials as Templates for Semiconductor Nanowire Assembly
Holmes, JD; Morris, MA; Ryan, KM (2003) Macroporous Materials as Templates for Semiconductor Nanowire Assembly. Self Assembly :175-183
Edited Books
Other Journals
High density and patternable growth of silicon, germanium and alloyed SiGe nanowires by a rapid anneal protocol
Bezuidenhout, M and Kennedy, T and Belochapkine, S and Guo, Y and Mullane, E and Kiely, PA and Ryan, KM (2015) High density and patternable growth of silicon, germanium and alloyed SiGe nanowires by a rapid anneal protocol. Journal of Materials Chemistry C :7455-7462
Conference Publications
GREENLION Project: Advanced Manufacturing Processes for Low Cost Greener Li-Ion Batteries
de Meatza, I,Miguel, O,Cendoya, I,Kim, GT,Loffler, N,Laszczynski, N,Passerini, S,Schweizer, PM,Castiglione, F,Mele, A,Appetecchi, GB,Moreno, M,Brandon, M,Kennedy, T,Mullane, E,Ryan, KM,Cantero, I,Olive, M,Briec, E,Muller, B (2015) GREENLION Project: Advanced Manufacturing Processes for Low Cost Greener Li-Ion Batteries. Electric Vehicle Batteries: Moving From Research Towards Innovation: Reports Of The Ppp European Green Vehicles Initiative :45-60
Silver Tip Formation on Colloidal CdSe Nanorods by a Facile Phase Transfer Protocol
Bala, T,Ryan, KM,Giri, PK,Goswami, DK,Perumal, A (2013) Silver Tip Formation on Colloidal CdSe Nanorods by a Facile Phase Transfer Protocol. Proceedings Of The 25th International Conference On The Physics Of Semiconductors, Pts I And Ii :21-31
Water Dispersible Semiconductor Nanorod Assemblies Via a Facile Phase Transfer and Their Application as Fluorescent Biomarkers
Sanyal, A,Ryan, KM,Giri, PK,Goswami, DK,Perumal, A (2013) Water Dispersible Semiconductor Nanorod Assemblies Via a Facile Phase Transfer and Their Application as Fluorescent Biomarkers. Proceedings Of The 25th International Conference On The Physics Of Semiconductors, Pts I And Ii :95-110
STATE-OF-THE-ART PROGRAM ON COMPOUND SEMICONDUCTORS 51 (SOTAPOCS 51) -AND- WIDE-BANDGAP SEMICONDUCTOR MATERIALS AND DEVICES 10
O'Sullivan, C,Gunning, RD,Barrett, CA,Singh, A,Geaney, H,Sanyal, A,Ahmed, S,Bala, T,Ryan, KM,Stokes, E,Goldhahn, R,Hunter, G,ODwyer, C,Ambacher, O,Huang, J,Kohn, E,Overberg, ME (2009) STATE-OF-THE-ART PROGRAM ON COMPOUND SEMICONDUCTORS 51 (SOTAPOCS 51) -AND- WIDE-BANDGAP SEMICONDUCTOR MATERIALS AND DEVICES 10. Ecs Transactions :17-29
ECS Transactions
O'Sullivan C., Gunning R.D., Barrett C.A., Singh A., Geaney H., Sanyal A., Ahmed S., Bala T., Ryan K.M. (2009) ECS Transactions. Ecs Transactions :17-29
ECS Transactions
Ahmed S., Barrett C.A., O'Sullivan C., Sanyal A., Geaney H., Singh A., Gunning R.D., Ryan K.M. (2009) ECS Transactions. Ecs Transactions :209-219
Materials Research Society Symposium Proceedings
Ryan K.M., Ahmed S. (2009) Materials Research Society Symposium Proceedings. :36-40
Conference Contributions
Published Reports
Editorials
Book Reviews
Other Publications
Two-dimensional copper based colloidal nanocrystals: synthesis and applications
Kapuria, N;Patil, NN;Ryan, KM;Singh, S (2022) Two-dimensional copper based colloidal nanocrystals: synthesis and applications. CAMBRIDGE : ROYAL SOC CHEMISTRY Nanoscale :2885-2914
Review-Use of Impedance Spectroscopy for the Estimation of Li-ion Battery State of Charge, State of Health and Internal Temperature
Carthy, KM;Gullapalli, H;Ryan, KM;Kennedy, T (2021) Review-Use of Impedance Spectroscopy for the Estimation of Li-ion Battery State of Charge, State of Health and Internal Temperature. PENNINGTON : ELECTROCHEMICAL SOC INC Journal Of The Electrochemical Society
Production and isolation of pharmaceutical drug nanoparticles
Verma, V;Ryan, KM;Padrela, L (2021) Production and isolation of pharmaceutical drug nanoparticles. AMSTERDAM : ELSEVIER International journal of pharmaceutics
Metal chalcogenide semiconductor nanocrystals synthesized from ion-conducting seeds and their applications
Kapuria, N;Ghorpade, UV;Zubair, M;Mishra, M;Singh, S;Ryan, KM (2020) Metal chalcogenide semiconductor nanocrystals synthesized from ion-conducting seeds and their applications. CAMBRIDGE : ROYAL SOC CHEMISTRY Journal Of Materials Chemistry C :13868-13895
Compound Copper Chalcogenide Nanocrystals
Coughlan, C,Ibanez, M,Dobrozhan, O,Singh, A,Cabot, A,Ryan, KM (2017) Compound Copper Chalcogenide Nanocrystals. Chemical Reviews :5865-6109
Self-assembly of CuInS2 and CuIn1-xGaxS2 nanorod into 2D and 3D superstructure
Singh, A,Coughlan, C,Geaney, H,Kelly, D,Ryan, KM (2012) Self-assembly of CuInS2 and CuIn1-xGaxS2 nanorod into 2D and 3D superstructure. Abstracts Of Papers Of The American Chemical Society
Facile spin-cast route for cation exchange of multilayer perpendicularly-aligned nanorod assemblies
Kelly, D,Singh, A,Barrett, CA,O'Sullivan, C,Coughlan, C,Laffir, FR,O'Dwyer, C,Ryan, KM (2012) Facile spin-cast route for cation exchange of multilayer perpendicularly-aligned nanorod assemblies. Abstracts Of Papers Of The American Chemical Society
High density germanium nanowire growth directly from copper foil by self-induced solid seeding
Geaney, H,Dickinson, C,Ryan, KM (2012) High density germanium nanowire growth directly from copper foil by self-induced solid seeding. Abstracts Of Papers Of The American Chemical Society