Dendrites

The most important thing to remember when dealing with the solidification of metals is that it is not sudden throughout the entire liquid. As molten pure metal soidifies, crystals start to form and these crystals grow by the addition of atoms to form a dendrite which as can be seen be is a crystal skelton with a backbone from which arms grow in other directions, fixed by the regularity of the unit cell.The growth of a tree , starting from its trunk and growing branches and twigs, is often used as an analogy to describe dendritic growth.
The dendrites grow outwards until contact is made with neighbouring growths and this contact surface becomes the boundary of the crystal or grain.
Click here to see the dendrites growing.
It should benoted that any impurities in the metal are both pushed by the growing crystal to the grain boundaries and trapped between the arms of the dendrites.