Eutectic Alloys

 The Second type of alloy combination we will look at is eutectic alloys.
The solid solution equilibrium diagram discussed in the last section was formed by two metals being totally soluble in both the liquid and solid states. A Eutectic equilibrium diagram results when the two metals are soluble in the liquid state but insoluble in the solid state. In the liquid state the two metals are soluble in each other but when cooling is complete, the grain of the solid alloy consist of two distinguishable metals which can be seen under a microscope to be like a layer of one metal on top of a layer of the other metal. This situation is completely different where the cooled solid grains look just like one metal when viewed under a microscope. In order to fully understand this type of alloy combination we will look at the Cadmium/ Bismuth Eutectic thermal eqlibrium diagram.
 

Cadmium- Bismuth Eutectic thermal equilibrium diagram

Cadmium and Bismuth are completely soluble in the liquid state, but are completely insoluble in the solid state. Lets take look at the diagram and then we will discuss it.

If you want to see how eutectic diagrams are created click here


The first and most noticable point on this diagram  is the Eutectic point. The eutectic point as can be seen above is a point in the diagram where the liquid alloy changes to a solid without going through a pasty state. This is the lowest melting point of any composition for the alloy.

The Diagram below will aid you in your understanding of what happens in the different zones in the eutectic thermal diagram.

As you would except everything above the liquidus line is in the liquid state and in this state the two metals are totally soluble in each other.
In the eutectic point  region (represented by the green line) there is only the eutectic composition alloy .
If you look at 100% Cadmium you will see that there is a large amount of solid Cadmium while this decreases in the alloys found nearer to the eutectic. The same applies for Bismuth. Therefore we can say that as the composition of the alloy moves away from the eutectic composition, grains of either Cadmium or Bismuth appear in the eutectic matrix.
 
 

You are now ready to move on to the next tpye of alloy combination i.e Partial solubility.

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